Yes, they are. For example Awakened Tit buff gives 50% DA buff and 30% TA buff, so with normal Kamihime it'd be 58% chance for DA and 33% for TA, which leaves 9% for single attack.
As for buffs stacking with each other, it depends on buff frame. DATA buffs rarely stacks (for example Awakened Tit buff will overwrite Herc's DATA buffs). I assume here that Ares AW assist stacks with Awakened Tit buff (or any DATA buff in general), which so far seems to be the case.





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