Also, if you have one Hime who is on a completely different level from your other Hime (such as Uriel or SSR Cybele can be, in lower quality teams), then putting that Hime as the last one is alright too. Since you can use that Hime to generate 10 burst for the rest of the team, and still catch up for Full Burst.
These are rather rare cases, though. Most of time, yes, from fastest to slowest.